Froggystyle
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Fiber Reinforced Plastics (FRP) was first applied to custom boats in the middle part of last century. It had been used in some industrial applications earlier, but it was the California boat scene that began the wholesale use of FRP in boat hulls. What a huge performance and utility upgrade from wooden boats! Far lighter, far stronger, far more durable.
The process, called "wet lamination" was easy enough to implement. You build a mold, which could be easily created from your wooden boat design you already may have as a female version of the boat you want to build. You wax the mold so your parts will release, gelcoat your mold and begin the laminates. You usually do what is called a "skin coat" of essentially non-structural Chopped Strand Mat (CSM) to prevent a thing called transfer and then start laminating. You soak fiberglass cloth in varying thicknesses in catalyzed resin (a two part plastic that gets hard) and lay it into the boat, rolling out any air bubbles with your fingers and various lamination tools. With enough resin, you can pretty much eliminate all "dry" spots and continue laminating one over another until you achieve your desired total thickness...
Let's talk about resin for a minute...
Resin is a set of long polymer chains that have what amounts to open sockets on them. They won't bond to each other because there is nothing in the resin to allow these "sockets" to attach to other "sockets", so they float around in a fluid manner. A large percentage of resin is comprised of various thickeners and thinners. Styrene is a major component of most resins, as are various petroleum based thickeners that make it easier to laminate with.
Catalyst comprises a bunch of "plugs" that like the "sockets" in the resin, won't join with each other. It stays fluid until combined. There are as many different types of catalysts as there are resins, but we will stick to the basics.
Also included in the mixture, but not usually controlled by boat builders is a promotion agent. We promote resin ourselves to control our mixture even better, and we use a product called "Cobalt" but I won't get into it. Essentially, it is an accelerator that will alter the speed at which the catalyst and resin react with each other, and at what heat.
Here comes the magic... Once you add the correct amount of catalyst to the resin it starts a chain reaction that allows the sockets of the resin to join with the plugs of the catalyst. As they are spinning into position at a molecular level, it develops heat. In the business, this is called an "exothermic" reaction. Each one of those molecules once joined is a small little bit of rigid material at the molecular level. As you get more and more of these small things becoming rigid, it takes more and more friction to get them to spin around and lock into each other. This generates even more heat. Left to its own devices in a large volume, normal General Purpose (GP) resin will exotherm to well over 350 degrees, enough to burn buckets and floors.
The resin, as stiff and rigid as it is, is barely structural on its own. It is brittle and unreinforced. Ponds of resin are weak spots in composites, and wet lamination is a strange balance between trying to add enough resin to make sure it is all the way wet, and pulling enough out to keep weight down and strength as high as can be expected.
The process, called "wet lamination" was easy enough to implement. You build a mold, which could be easily created from your wooden boat design you already may have as a female version of the boat you want to build. You wax the mold so your parts will release, gelcoat your mold and begin the laminates. You usually do what is called a "skin coat" of essentially non-structural Chopped Strand Mat (CSM) to prevent a thing called transfer and then start laminating. You soak fiberglass cloth in varying thicknesses in catalyzed resin (a two part plastic that gets hard) and lay it into the boat, rolling out any air bubbles with your fingers and various lamination tools. With enough resin, you can pretty much eliminate all "dry" spots and continue laminating one over another until you achieve your desired total thickness...
Let's talk about resin for a minute...
Resin is a set of long polymer chains that have what amounts to open sockets on them. They won't bond to each other because there is nothing in the resin to allow these "sockets" to attach to other "sockets", so they float around in a fluid manner. A large percentage of resin is comprised of various thickeners and thinners. Styrene is a major component of most resins, as are various petroleum based thickeners that make it easier to laminate with.
Catalyst comprises a bunch of "plugs" that like the "sockets" in the resin, won't join with each other. It stays fluid until combined. There are as many different types of catalysts as there are resins, but we will stick to the basics.
Also included in the mixture, but not usually controlled by boat builders is a promotion agent. We promote resin ourselves to control our mixture even better, and we use a product called "Cobalt" but I won't get into it. Essentially, it is an accelerator that will alter the speed at which the catalyst and resin react with each other, and at what heat.
Here comes the magic... Once you add the correct amount of catalyst to the resin it starts a chain reaction that allows the sockets of the resin to join with the plugs of the catalyst. As they are spinning into position at a molecular level, it develops heat. In the business, this is called an "exothermic" reaction. Each one of those molecules once joined is a small little bit of rigid material at the molecular level. As you get more and more of these small things becoming rigid, it takes more and more friction to get them to spin around and lock into each other. This generates even more heat. Left to its own devices in a large volume, normal General Purpose (GP) resin will exotherm to well over 350 degrees, enough to burn buckets and floors.
The resin, as stiff and rigid as it is, is barely structural on its own. It is brittle and unreinforced. Ponds of resin are weak spots in composites, and wet lamination is a strange balance between trying to add enough resin to make sure it is all the way wet, and pulling enough out to keep weight down and strength as high as can be expected.